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Translations for „cyclization“ in the Russian » English Dictionary (Go to English » Russian)

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English
Metal-catalyzed cyclization reactions usually require mildly basic conditions, and substrates must be chosen to avoid -hydride elimination.
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The cyclization of -epoxy-1-nitriles provides an interesting example of how stereoelectronic factors may override steric factors in intramolecular substitution reactions.
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Both lanosterol and cycloartenol are derived via cyclization of the triterpenoid squalene.
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A classic example is the cyclization of geranyl pyrophosphate to form limonene.
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The dimethylallyl group in 7 then undergoes cyclization with the phenol group to give 8.
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In this pathway, vinblastine is constructed by a series of cyclization and coupling reactions which create the required stereochemistry.
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Other applications include use in alkylation reactions and as a catalyst component in linear oligomerization and cyclization of unsaturated hydrocarbons.
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The resulting o-benzoylbenzoic acid then undergoes cyclization, forming anthraquinone.
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Approaches to this synthesis are diverse, and include central steps such as annululation, olefin metathesis, radical cyclization, and trapping reactions.
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The polyketide chain produced is electronically capable to go through a lactonization and a diels alder cyclization, as shown below.
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