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Translations for „steric“ in the English » Arabic Dictionary (Go to Arabic » English)

Monolingual examples (not verified by PONS Editors)

English
Clear-cut cine-substitution would give a 1:1 ratio but additional steric and electronic factors come into play as well.
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The 1,4- isomer is preferred over the 1,2- isomer due to steric hindrance.
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Interestingly this is an example with extreme stereoselectivity due to the severe steric hindrance of an ethano-bridge.
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Strict steric constraint exists around the pyrrolidine ring of cyanopyrrolidine-based inhibitors, with only hydrogen, fluoro, acetylene, nitrile, or methano substitution permitted. 2.
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In addition, nucleophiles always attacks the secondary carbon of the oxirane ring because of stability of the intermidiate and steric hindrance.
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Nevertheless, some reactions exhibit steric factors greater than unity: the harpoon reactions, which involve atoms that exchange electrons, producing ions.
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The steric interaction between the pyrrolidine ring and the electrophilic reagent hinders the attack of the electrophile from the top face.
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Formaldehyde reacts with water so readily because its substituents are very small- a purely steric effect.
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By controlling the stoichiometry and steric properties of the alkoxide, such reactions can be arrested leading to metal-oxy-alkoxides, which usually are oligonuclear complexes.
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As steric hindrance around the electrophilic center increases, as with isobutyl bromide, substitution is disfavored and elimination is the predominant reaction.
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