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Translations for „stereoelectronic“ in the English » Polish Dictionary (Go to Polish » English)

stereoelectronic CHEM

Monolingual examples (not verified by PONS Editors)

English
Stereoelectronic effect generally includes a donoracceptor interaction.
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It was subsequently shown that the increase in stability is primarily through stereoelectronic effects and that hydration of the hydroxyproline residues provides little or no additional stability.
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Stereoelectronic effect can be directional in specific cases.
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The cyclization of -epoxy-1-nitriles provides an interesting example of how stereoelectronic factors may override steric factors in intramolecular substitution reactions.
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Interestingly, the migrating substituent is determined by a stereoelectronic effect where the group trans to the lone pair on the nitrogen will always be the predominant migration product.
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Typical stereoelectronic effects with specific orbital overlaps generally lead to a specific molecular conformation, or energy differentiation among various transition states which would lead to a particular reaction selectivity.
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